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The MCAT Course Syllabus

Learning Environment
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Diagnostic Testing & Goal Management



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Any Wisebridge printed item is also available as a free download which may be freely copied for commercial or noncommercial purposes.

Wisebridge Publications are much, much less expensive than ink jet cartridges, even less expensive for teachers than using the school copier . Our books are nicely bound and well thought out in every way.

Every printed version is accompanied by a free DVD containing every publication of the WikiPremed Project. The DVD is also free to any teacher anywhere in the world who requests a copy of it.

This syllabus will soon be populated with links to a large quantity of free learning materials, a matter of a few days. The present learning tasks do not reflect all the free stuff I have decided to make available, but changing anything to do with this course is a like turning a big ship. It is coming in. I promise you will not be waiting on the dock very long. Stay and read the syllabus, especially the learning goals and try to understand how the Main Cycle, Overview, and Interdisciplinary goals will be working together. I have live students hearing a session on the first module next Monday in Atlanta. Although we will be meeting every other week for ten months, there are students in my live course preparing for the August exam, so you can rest assured things will be ready for anybody starting their MCAT preparation here today.

For the learning tasks, you can see how my works listed on the home page are going to fit in here. I have not made everything you need. You still need a big MCAT book because I decided ten years ago not to create works someone else had already done well enough, so although I have a complete set of physical sciences problem sets, which I composed in 1993 and 1994, I released myself from the burden of writing 500 organic problems. I had other things to do. The Kaplan Book is good, but the ExamKrackers set is better, although it is three times more expensive. You are fine with pretty much any combination of MCAT books that is at least five inches tall on the desk. We will use them for topical problem drill and conceptual cycling and that is about it. The first four modules will soon have links within all the learning tasks to WikiPremed creative commons materials you will be able to download, actually Wednesday barring unforeseen developments.
Main Sequence     Overview Cycle     Interdisciplinary Discussions     Verbal Reasoning     Essay

Module 4 - Matter at the Atomic, Molecular and Intermolecular Levels

We are at an important stage in the course in terms of both logistics and the curriculum. At the fourth module you have come far enough to be able to make informed judgments about your routine and make adjustments if they are necessary. Take a moment to reflect on your study methods. Are your learning materials working for you? Does your schedule fit well into your life? Do you feel confident about the learning process? It is still not too late to find a study group. Are you getting enough regular sleep? Reflect on how things feel and make adjustments to improve the quality of your learning. Sieze the opportunity. Don't just let the wind carry you.

In teaching my small group course over the years, I have always tried to encourage my students to think of preparing for the MCAT as more than just a hurdle to cross. Preparing for this exam is more than just another achievement goal. Sure, it's important in that down-to-earth practical sense. This is your life after all. I am not down-rating a practical approach to things, but what I mean to get across is the sense that preparing for the MCAT is your opportunity to gather up the knowledge you have worked hard to gain throughout your undergraduate years and form it into true mastery. Preparing for the MCAT is your chance to build a structured knowledge base that you will be proud to bring to medical school. Truly, I admire the designers of the science sections of the MCAT because they have managed to create an exam with very little difference between the answer to the question 'Will this be on the test?' and the answer to the question 'Do I need to know this for medical school?'. Consider how both questions are important for you, but in different ways. Thinking about the test will make you sit down and study. Thinking about what's coming up for you in medical school will awaken your intelligence while you are studying.

Module 4 - Overview

Main Sequence - Atomic Theory, Periodic Properties, Chemical Bonding, and Intermolecular Forces.

Overview - Make a second complete survey of General Chemistry.

Interdisciplinary Discussions - The discussions this module focus on developing your ability to use classical Physics to help you better understand Atomic Theory, Chemical Bonding, and Intermolecular Force.

Verbal Reasoning and Essay - Reading program, exercises, and writing assignment.

Module 4 - Main Sequence        { 12 - 15 hours }

We have reached a transition in the Main Sequence. We are ready to begin General Chemistry. Take a few minutes to get your bearings, a few moments to think carefully about what we have covered so far, the fundamental topics of Mechanics, the special topics in Mechanics, and the fundamental forces of Gravity and Electricity. You have reviewed the basic behaviors and interactions of physical bodies.

.The material we covered in the first three modules is core MCAT knowledge, and the first three modules of the course are also important in that they have prepared us for Module 4. We are now ready to begin our study of matter in Chemistry. We are ready to understand the structure of matter and the transformations it can undergo. We our ready to begin General Chemistry! Your fresh understanding of Motion & Force, Work & Energy, and Electricity gained from your recent review of Physics will now serve you as an intuitive basis for understanding the structure of matter. The basic Physics is the foundation of conceptual imagination in Chemistry.

As you study the changes that matter can undergo in General Chemistry, it is absolutely essential that you continuously make yourself step back and 'defamliarize' the phenomona. Get out of the Chem 101 mindset. A curse on the Chem 101 mindset! When you learn to see Chemistry in terms of the more fundamental principles of Physics, even the classical Physics with all of its limitations in the quantum world, you will awaken a much more conceptually intuitive understanding. If your college is like most colleges, for better or for worse, you have probably learned General Chemistry without having much Physics in the discussion. This practice of teaching General Chemistry without Physics is the bane of my existence. It is the result of how universities are organized not how the universe is organized. In fact, approaching Chemistry through Physics makes understanding Chemistry much, much easier. Below are our Main Sequence topics for Module 4:








Atomic Theory is the branch of chemistry concerned with the smallest form of an element that can exist chemically, the atom. Classical physics is helpful to understanding some properties of atoms. However, the range of behaviors of atoms exceeds the descriptive powers of classical physics. To explain the line spectrum of hydrogen, for example, Neils Bohr develped his early form of atomic theory. A more complete picture of the electronic structure of the atom is provided by modern quantum electrodynamics.



Atomic Theory on the MCAT

Questions directly concerned with Atomic Theory, or more generally, basic quantum mechanics, do appear with fair regularity on the MCAT, although they tend to be easier questions than they may seem at first glance. More important than the direct appearance of these concepts on the exam is that these initial chapters of Chemistry, dealing with the instrinsic structure of matter, i.e. Atomic Theory, Periodic Properties, and Chemical Bonding, are absolutely crucial for the scientific understanding of the physical and natural world. The rest of General Chemistry, Organic Chemistry, and Biology will make profoundly better sense, and be much more interesting besides, if you take special care to understand the structure of matter.


Learning Goals for Atomic Theory


Gain comfortable familiarity with the apparatus, mechanisms and conclusions of the most significant experiments of early modern Atomic Theory including J.J. Thomson's cathode ray experiment, Millikin's oil drop experiement, and Rutherford's experiment with gold foil and alpha rays.
Understand the consequences of Planck's experiment with black body radiation.
Be able to verbally reproduce the reasoning from evidence that led to Bohr's model of the hydrogen atom.
Master the basic description of the electronic structure of the atom in modern quantum theory in terms. Picture the orbitals of an atom. Understand how to use quantum numbers to describe them, the Pauli exclusion principle, the aufbau principle and Hund's rule.

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Suggested Assignments


Spend a half-hour in the Atomic Theory chapter of your college chemistry textbook. Read the bold headings, formulas, and summaries. Get a clear mental picture of the important experiments in the history of Atomic Theory, the Bohr model, and the atomic orbital model of the electronic structure of the atom.
Carefully study the Atomic Theory section of your Main Sequence Book.
Perform a set of ten to twenty MCAT style multiple-choice questions in Atomic Theory. Your Main Sequence Book should have topic specific problems. The Wisebridge Physical Sciences Questions for the MCAT also contains a set for Atomic Theory.
Review the Atomic Theory external resources within the Exploration Environment.

Activate the syllabus for task and goal management      






The periodic table is an arrangement of the chemical elements ordered by atomic number in columns and rows (groups and periods). The design of the periodic table reflects the observation that many properties of the chemical elements are periodic functions of their atomic number. The periodic table is arranged so as to emphasize these periodic properties. In concert with an atom's valence shell configuration, the periodic properties of an element provide you with a thumbnail picture of its tendencies, allowing you to predict how it will behave in different contexts. The periodic properties are atomic radius, ionization energy, electron affinity and electronegativity.


Periodic Properties on the MCAT

Only rarely to questions appear on the MCAT that ask you directly about periodic properties, but like so many of these early chapters, the material is fundamental to much else which comes later. Of the periodic properties, the electronegativity is especially crucial, although all of them are important. Considering the electronegativity difference between bonded atoms is the first step to assigning bond polarity. Understanding bond polarity is necessary for predicting intermolecular forces, solubility relationships or assigning oxidation numbers, for example.

Learning Goals for Periodic Properties


Check off your learning goals when completed.
Understand the rationale behind the organization of the periodic table and how the organization of the table relates to electronic structure.
Be able to define atomic radius and predict the relative sizes of atoms from their position on the periodic table.
Model the events described by electron affinity as well as ionization energy in your imagination. Understand the patterns of change in the energy involved for these events moving from left-to-right and up-and-down across the periodic table.
Clearly comprehend the context and meaning of electronegativity and how it changes across the periodic table.
Be sure to have memorized the values of the electronegativities of the important elements of organic chemistry including carbon, hydrogen, oxygen, nitrogen, and the halogens (and some of the alkali metals and sulfur and phosphorus too).

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Suggested Assignments


Carefully study the Periodic Properties in your Main Sequence Book. The core concepts in your Main Sequence book must be mastered completely.
Read the bold headings, formulas, and captions of the Periodic Properties chapter of a good college chemistry textbook.
Perform a set of ten to twenty MCAT style multiple-choice questions in Periodic Properties from your Main Sequence Book. There is also a Periodic Properties problem set in the Wisebridge Physical Science Questions for the MCAT.
Finish your Main Sequence work on the Periodic Properties with a good, thorough review of the Periodic Properties external resources in the Exploration Environment.

Activate the syllabus for task and goal management      






Chemical bond is a term used to describe the range of different types of attractions that can occur to allow two or more atoms to become persistently associated and take on properties as a group. Although there aren't clear distinctions at the boundaries, there are basically three types of chemical bonds: metallic, ionic, and covalent.

In pure metals and many alloys, the outermost s and p electrons become freely mobile, forming a kind of electron 'fluid'. Metallic bonding describes the attractions between the lattice of positively charged metal ions and the surrounding mobile electrons.

Ionding bonding results from the transfer of electrons from one species to another. The bond is the resulting attraction between the cation and anion formed.

Covalent bonds result when atoms share a pair of electrons. The bond consists of the attraction of the electron pair in the internuclear space for the nuclei of the bonded atoms.



Chemical Bonding on the MCAT

Although you will probably see a few traditionally framed chemical bonding questions on the MCAT, no other topic is more important for your overall goals in MCAT preparation in the sciences. Huge portions of the general chemistry, organic chemistry, and biology can only be coherently understood if you understand the fundamentals of chemical bonding.

Learning Goals for Chemical Bonding


Check off your learning goals when completed.
Be able to distinguish the differences between ionic bonding, covalent bonding, and metallic bonding.
Understand the forces involved and the story of energy in covalent bond formation. Be able to answer questions like: What holds the bonded atoms together? What happens to electrostatic potential energy when a bond is formed?
Master the traditional valence approach for basic problem solving including the octet rule, drawing Lewis structures, and assigning formal charge.
Develop at least introductory level comfort with molecular orbital theory.
Be prepared to comfortably discuss the concepts of molecular orbital hybridization especially as they relate to organic chemistry.
Understand resonance and how to predict the contribution of resonance structures in molecular forms.
Gain facility in applying valence shell electron pair repulsion theory (VSEPR) to predict molecular geometries.
Differentiate polar and nonpolar covalent bonds. Be able to recognize the polar and nonpolar covalent bonds in a structural formula.

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Suggested Assignments


Carefully study the Chemical Bonding section of your Main Sequence Book. MCAT review materials tend to be more spare than they should with this topic, in my opinion. Save time for your college textbook and the resources of the Exploration Environment.
Take a careful review tour of the Chemical Bonding resources in the Exploration Environment. The Chem1 Virtual Textbook is especially excellent for MCAT preparation.
Review the Chemical Bonding chapter of a good college physics textbook. This is a topic where the scale of treatment in a textbook is a good match for the MCAT. You need to really dig in to understand covalent bonding in terms of force and energy.
Perform a set of MCAT style questions in Chemical Bonding. Your Main Sequence Book should have a problem set, and you can find one in the Wisebridge Physical Science Questions for the MCAT.

Activate the syllabus for task and goal management      






Intermolecular forces occur between molecules. Although intermolecular forces are weaker than chemical bonds, they are very significant in determining the physical and chemical properties of substances. There are three principal types of intermolecular force: 1) dipole-dipole forces, which occur between polar molecules 2) London dispersion forces, which occcur due to small instantaneous dipoles and 3) hydrogen bonding, which occur between molecules in which hydrogen is bonded to a small electronegative atom such as oxygen. Because the polarity of such molecules is occupied on one end by a bare hydrogen proton, without inner shells of electrons to shield it, hydrogen bonding gives rise to intermolecular forces which are significantly stronger than any other type.



Intermolecular Forces on the MCAT

Because intermolecular forces are of great importance in living organisms, this topic is of major MCAT importance. The MCAT will often pose both explicit questions from this topic and questions depending on reasoning which takes intermolecular force as its starting point. Furthermore, many other topics, such as States of Matter or Solutions in Chemistry or Proteins or Membranes in Biology greatly rely on your understanding of Intermolecular Forces.

Learning Goals for Intermolecular Forces


Be sure you can comfortably characterize the three kinds of intermolecular force.
Develop the skill to predict the type of intermolecular force which will predominate within a substance if presented with the structural form of a molecule.
Understand the role played by intermolecular force in determining the physical properties of a substance and its solubility in various solvents.

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Suggested Assignments


Carefully study the Intermolecular Forces section of your Main Sequence Book.
Thoroughly read the Intermolecular Forces sections of either your college chemistry textbook or your organic chemistry textbook. It won't be more than a few pages. This is an important topic, so you definitely want to make sure you understand.
Your Main Sequence Book may have problems specifically dedicated to Intermolecular Forces. If so, that's good. If not, self-assess to make sure that if presented with a structural formula, make sure you can properly assign the type of intermolecular force.
Take a review tour of the Intermolecular Forces resources in the Exploration Environment to make sure you have this important topic down.

Activate the syllabus for task and goal management      





Module 4 - Overview Cycles        { 3 - 5 hours }

Our Overview Cycle work this module is to perform the second half of our two module grand tour of the physical science sections of Alfa Diallo's excellent MCAT Pearls. In the second module of the course we completed the first half of this tour with Physics. This module you will read the MCAT Pearls entries on General Chemistry from beginning to end. Pace yourself to get through it in less than 3 hours. As you make your way through this Overview Cycle, be sure to keep the Overview Cycle frame of mind. Get through it and don't get bogged down. In an Overview Cycle, you are walking around the mountain and surveying it, not tunneling through it. Take the long view.


Overview Cycle - Learning Goals


Be able to fluently reproduce the outline of General Chemistry at the main topic level.
Understand the phenomena described within each main topic of General Chemistry in terms of the model systems and fundamental concepts discussed.

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Suggested Assignments


Review the Chemistry at MCAT Pearls, starting HERE. Read a discussion until you have good comprehension. Then move on. Set your pace to complete this task in no more than 3 hours. Keep your forward momentum. Get through it!
Like the third module of the course, spend some time practicing with the outline below to get nearer to being able to reproduce it in full if given a blank sheet of paper. If you are not sure how to go about this, just sit down and write them out two or three times.

Activate the syllabus for task and goal management      

THE STRUCTURE OF MATTER
Atomic Theory
Periodic Properties
The Chemical Bond
Intermolecular Forces
STOICHIOMETRY
Stoichiometry
CHEMICAL THERMODYNAMICS AND CHEMICAL KINETICS
Thermochemistry
The States of Matter
Chemical Thermodynamics and the Equilibrium State
Chemical Kinetics
SOLUTIONS AND AQUEOUS SYSTEMS
Water
Solutions
Acids and Bases
OXIDATION REDUCTION AND ELECTROCHEMISTRY
Oxidation/Reduction
Electrochemistry
COORDINATION CHEMISTRY
Coordination Chemistry




Module 4 - Interdisciplinary Discussions        { 3 hours }

From our Main Sequence point of view within the Structure of Matter: Atomic Theory, Periodic Properties, Chemical Bonding, and Intermolecular Forces, this module the Interdisciplinary Discussions look back toward the portions of classical physics we have already covered to discuss the forces involved in chemical systems and the energy tranformations that occur in chemical change. In other words, a major theme this module will be to discuss Newton's Laws, Work & Energy, and Electricity in the context of the fundamental structure of matter.

In the few Interdisciplinary Discussions associated with Atomic Theory, we will try to develop a sense of how to benefit from classical physics reasoning in the light of quantum mechanics.

In addition to looking back towards classical physics, another major theme in the discussions this module will be to look ahead toward later chemistry topics. We introduce Thermochemical reasoning this module within our discussion of Periodic Properties, Chemical Bonding, and Intermolecular Forces. Additionally, several discussions are the start of a long thread in the discussions we will pull numerous times in the months ahead. This is the theme of Oxidation-Reduction in the context of the energy description of Chemical Bonding.

Before you begin these discussions, take a sheet of plain paper and write down the following formula in big, bold letters to keep on the desk.




This is the formula for electrostatic potential energy from classical physics. It describes the state of potential energy that exists in a system of two point charges. Although chemical systems are quantized, the classical picture is useful as thumbnail representation of energy changes. What does the formula tell you about opposite charges as they are drawn closer together? (Potential energy falls down into the well of binding energy, a negative number that gets more and more negative). What does the formula tell you about like charges pushed together? (Potential energy rises, reflecting the work you are doing to push the charges together)

As you make your way through the Interdisciplinary Discussions associated with Atomic Theory, Periodic Properties, Chemical Bonding, and Intermolecular Forces, any time you read the word 'energy' stop and look over at this formula then imagine the chemical system in a defamiliarized way as an arrangement of charged particles. Try to see a single atom with its nucleus and electrons, two bonded atoms in a covalent bond, or the molecules associated by intermolecular forces as systems of charged particles. Imagine like charges being pushed together or unlike charges pulled apart as you imagine the changes these systems can undergo. Look at the formula and think about what is happening with energy in things like the ionization of an atom, the formation of a chemical bond, or the condensation of a vapor.

Interdisciplinary Discussion - Learning Goals


Use classical physics to build your intuition of chemistry (even in the light of quantum mechanics).
Model changes at the level of single atoms, bonded atoms, and molecules interacting through intermolecular force in terms of Work & Energy and Electricity. Understand the concept of binding energy in the context of each of these levels of the structure of matter.
Through an understanding of changes in energy during covalent bond formation, begin to understand why the graph of the Electronegativities of the elements agrees with their Reduction Potentials.

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Suggested Assignments


Read the Interdisciplinary Discussions for Atomic Theory, Periodic Properties, Chemical Bonding, and Intermolecular Forces slowly and carefully. They start a bit slow in Atomic Theory with a few dedicated to items of historical interest, but things pick up in Periodic Properties. A half dozen of the discussions this module are absolutely crucial within the context of the spiraling curriculum, so don't zone out. Start HERE to begin the Interdisciplinary Discussions of Atomic Theory and then Click 'Next Discussion' until you reach the end of Intermolecular Forces.
For this module's concept mapping create one sheet relating Newton's Laws, Work & Energy, Electricity, and Chemical Bonding and one sheet relating Work & Energy, Electricity, Intermolecular Forces, and States of Matter.

Activate the syllabus for task and goal management      





Module 4 - Verbal Reasoning        { 2 - 3 hours }

Reading Program and Exercises

To help make you into a stronger reader, an important part of this Learning Program will be to spend a few hours approximately every other module reading difficult and interesting works. This will make your brain stronger.

Additionally, we have another exercise to help you understand the thinking processes of the people who write MCAT verbal reasoning questions.

Verbal Reasoning Tip of the Week

As you read a Verbal Reasoning passage, pay extra attention when you run into contrast words such as 'although', 'however', 'despite' or 'nevertheless' because there will almost always be a question coming from that. Take special stock of the content of the author's change of direction or the relationship between any counter-premise and the main idea.

Verbal Reasoning Assignments


Two or three times this module, sit down for one half hour and read from the following works in the category of BIOGRAPHY. Practice concentrating. Listen to the voice of the writing. Sustain your attention, and don't zone out. This will get easier and easier, as you develop your abilities for mindful reading through practice. Of course, you may want to set aside reading some of the works in their entirety that are quite long.

accessibleAdopting an Abandoned Farm - Kate Sanborn
moderateBoswell's Life of Johnson - James Boswell
difficultHawthorne - Henry James
Again this module, let's practice being an MCAT test writer. Write a 'correct' and an 'incorrect' answer corresponding to questions following a typical verbal reasoning passage. Pretend you are part of a committee making the test, and your job is to write a 'best answer' and a 'second best' (tricky but wrong) answer. Print and complete this exercise. Click Here.

Activate the syllabus for task and goal management      




Module 4 - Essay        { 1 hour }

This is your fourth essay. The keys to preparing for the essay are to learn a good technique and practice. In module 2 we discussed how to structure a unified critical MCAT essay. Here is a LINK to that discussion for a quick review.

Essay - Assignments - Module 4


Arrange an undisturbed half hour for yourself to write an essay. You need some plain ruled paper and an erasable pen. Skip lines to give yourself some flexibility for editing as you write. Click Here and the computer will present a PDF file containing your essay topic for module four. Don't advance to page 2 until you are ready to begin writing. If you would like to print out the PDF in order to write your essay away from the computer, be sure not to look at page 2 until you are ready to begin.

Activate the syllabus for task and goal management      




MECHANICS AND WAVES
link to syllabus
Kinematics1
Newton's Laws
Work, Energy, and Power
Momentum and Impulse
Rotation2
Harmonic Motion
Elastic Properties of Solids
Fluid Mechanics
Waves
FUNDAMENTAL FORCES
Gravitation3
Electricity
THE STRUCTURE OF MATTER
Atomic Theory4
Periodic Properties
The Chemical Bond
* * *Intermolecular Forces
Functional Groups in Organic Chemistry5
Conformations of Organic Molecules
Stereochemistry
THERMODYNAMICS AND KINETICS IN PHYSICAL AND CHEMICAL SYSTEMS
Temperature and Heat Flow6
The Ideal Gas and Kinetic Theory
The First Law of Thermodynamics
Stoichiometry
Thermochemistry
The Second Law of Thermodynamics and Heat Engines7
Chemical Thermodynamics and the Equilibrium State
The States of Matter
The Physical Properties of Organic Compounds
Chemical Kinetics
SOLUTIONS AND AQUEOUS SYSTEMS
Water8
Solutions
Acids and Bases
Organic Acids and Bases
ORGANIC REACTION CHEMISTRY
Nucleophiles and Electrophiles9
Intramolecular Cationic Rearrangements
Reactions with Radical Intermediates
Conjugated π Systems and Aromaticity
Reactions of Alkanes
Reactions of Alkenes
Reactions of Alkynes
Reactions of Alkyl Halides
Reactions of Allylic and Benzylic Conjugation
Reactions of Aromatic Compounds
Reactions of Alcohols and Ethers
Reactions of Aldehydes and Ketones
Reactions of Carboxylic Acids and Derivatives
Reactions of Amines
Reactions of Organic Phosphorus Compounds
Reactions of Organic Sulfur Compounds
BIOMOLECULES10 break
Proteins11
Carbohydrates
Nucleic Acids
Lipids
THE CELL
Biological Membranes
The Prokaryotic Cell
The Eukaryotic Cell
BIOENERGETICS AND BIOSYNTHESIS
Coordination Chemistry12
Oxidation/Reduction
Oxidation/Reduction in Organic Chemistry
Electrochemistry
Bioenergetics and Cellular Respiration
Photosynthesis  
Biosynthesis of Macromolecules
Integration of Metabolism
GENETICS & REPRODUCTION
Gene Expression13
Cellular Reproduction
Mendelian Genetics
Recombination and Mutation
The Molecular Biology Laboratory
Human Genetics
DIVERSITY OF LIFE
Viruses14
Monera
Protista
Fungi
Plants  
Animals
Animal Development and Embryology
Mammalian Tissues and Histology15
HUMAN PHYSIOLOGY
The Nervous System
Sensory Systems
The Endocrine System
The Musculoskeletal System
The Cardiovascular System
Blood
The Respiratory System
The Lymphatic System and Immunity
The Urinary System
The Digestive System and Nutrition
The Reproductive System
POPULATION BIOLOGY
Populations16
Evolution
Ecology
ELECTROMAGNETISM, LIGHT, AND MODERN PHYSICS
Electricity17
DC Current
Magnetism
Electomagnetic Induction
AC Current
The Properties of Light
Geometric Optics
Wave Optics
Modern Physics18
Molecular Spectroscopy
Nuclear Physics
19 break
20 break

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